Friday, September 6, 2019

Application of Ozone and UV radiation for disinfection of water

Application of Ozone to water supplies for disinfection
  • Ozone gas is a faint blue gas with pungent odour
  • It is an unstable allotropic form of oxygen with each molecule consisting of three oxygen atoms
  • It is produced by passing high tension electric current through a stream of air in a closed chamber.
  • Because of its instability, ozone readily breaks down into normal oxygen and releases nascent oxygen
  • The nascent oxygen so produced is a powerful oxidizing agent and removes organic matter as well as bacteria from water.
  • During treatment, ozone gas is manufactured and bubbled through water in a sterilizing chamber and ozonized water is removed through the outlet at the top.
  • Approximately 2 to 3 ppm of ozone is generally consumed to obtain a residual ozone of 0.1 ppm after a contact period of ten minutes
  • Ozone and chlorine are competitive disinfectants. Chlorine is preferred and universally accepted.
Advantages
  • Since ozone is unstable, nothing remains in water by the time it reaches the distribution system
  • Ozone removes colour, taste and odour from water, in addition to removal of bacteria
  • Ozonised water is tasty and pleasant unlike chlorinated water which becomes bitter to taste
Disadvantages
  • It is expensive when compared to chlorination
  • Ozone needs electricity for its manufacture and hence it can be used only in places where electricity is available easily and for a low cost
  • No residuals can be maintained because it is highly unstable and its use does not ensure safety against possible future contamination
  • Using ozone as a disinfectant requires complicated ozone manufacturing apparatus called ozonizer to be installed at the the treatment facility since ozone cannot be supplied in cylinders like chlorine
  • Ozone is not as efficient in disinfection as chlorine 
Treatment with Ultra-Violet radiation for disinfection
  • Ultra-Violet (UV) rays are invisible light rays having wave lengths of 1000 to 4000 micro-meters.
  • They are found in sunlight but can also be produced by passing electric current through Mercury enclosed in quartz bulbs.
  • Mercury vapour lamps enclosed in quartz bulbs can therefore be used as good source of such rays.
  • UV rays are highly effective in killing all types of bacteria thereby yielding truly sterilised water
  • Water to be treated with UV rays should be less turbid annd low in colour. Preferably the water should be colourless and turbidity should not exceed 15 mg/l.
  • In the process of using UV radiation to achieve disinfection, water is passed several times around quartz bulbs emitting UV rays.
  • Since the effective depth of penetration of UV rays is around 10cm, the depth of water over the bulbs should not exceed 10cm for efficient disinfection
Advantages
  • Sterilization with UV rays does not impart any additional taste or odour to water since no chemicals are added.
  • This method is used extensively for treatment of small quantities of water supply in hospitals and dispensaries for surgical purposes or drinking water purification units installed in homes and offices 
Disadvantages
  • It is a very expensive process and requires technical know-how
  • Possibility of interruption in process due to failure of electricity
  • It is not feasible to treat large scale water supplies 

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